5 axis 3D Printer

Your description of the problem does not make much sense.

Why would the number of serial ports have any relevance to a 3 D printer?

I don't think anyone would consider the extruders to be additional axes what you describe is a normal 3-axis printer.

AFAIK 3D printers with dual extruders are common. Have you looked on the RepRap Forum where they specialize in 3D printing.

...R