Multivibrators (Sorry girls, nothing to get excited at here... :) )

  1. On applying voltage, at the start, do both caps start charging..

Both charge up, but at different rate. The one that gets charged up first flips the other transistor first.

  1. Resistor 2 and 4 are both connected to the Minus side of the capacitors yet connected to a positive + rail... huh? why?

Those capacitors see reverse polarities so the polarity marking is likely to indicate that they are larger electrolytics. They should be non-polarity capacitors.