Confused on 1st hurdle. >>>Warning Noobie

electrofunkdaddy:
so in my really simple circuit. as above to switch the pin (say 13) output to HIGH and this switch's the LED on but wouldn't that apply another 5V to the diode, as well as the fixed 5v pin connected to the common diode?,

Yes. You'll have 5V on both legs of the LED.