Using PID library for heating element with SSR and max31855

  pinMode(RelayPin, OUTPUT);

Are you planning to set the mode of the relay pin to INPUT later in loop, so you can read the state of the relay? Seems unlikely. This belongs in setup().

What, exactly, are Input and Output in terms of the temperature read from the thermocouple? It appears that you are using Output as though it were some sort of measure of time. It is not.