@richardtheboffin
It depends on your gyro - some have to be orientated up others don't.
Regarding which axis you should use on your accelerometer: I can't say for sure. It depends on how it's orientated. Either it's X and Z or Y and Z.
Try to modify this code: https://github.com/TKJElectronics/Example-Sketch-for-IMU-including-Kalman-filter/blob/master/IMU6DOF/LPR530AL_%20LY530ALH_%20ADXL335/LPR530AL_%20LY530ALH_%20ADXL335.ino, so it's uses the correct sensitivity values for your setup.
Then afterwards you can easily see which angles should be fused together.
You might also need to invert some of the readings, as I have done here: https://github.com/TKJElectronics/Example-Sketch-for-IMU-including-Kalman-filter/blob/master/IMU6DOF/LPR530AL_%20LY530ALH_%20ADXL335/LPR530AL_%20LY530ALH_%20ADXL335.ino#L51