but's instead ,it shows that "Serial port is in use , try again" , What can I do? Should I try to Mount IC on GSM board again and try to connect it through RS232 interface with Arduino?
its a very basic problem you are facing here ,its obvious that when the UART is used to communicate with the sim300 module then at the same time it can't provide for communication between your serial monitor and the hardware so you have to use NewSoftwareSerial library that comes with the Arduino IDE simply it will form serial port on any other pin on the AVR uC.