The equation you need is:
Tj = Ta + (P * (Rjc + Rch + Rha))
where Tj is the junction temperature, Ta is the ambient temperature, P is the power dissipated in the device (which according to Mike is 5W), Rjc is the thermal resistance junction to case (0.9 degC/W from your triac datasheet), Rca is the thermal resistance case to heatsink, and Rha is the thermal resistance heatsink to ambient. The datasheet for a commercial heatsink will give you the value of Rha. You need to choose a heatsink with a low enough Rha such that Tj is below the device limit. See
http://www.jaycar.com.au/images_uploaded/heatsink.pdf for more.