That should be fairly easy. It is only 4 bits to the PLL internally. It can be sent as 3 8-bit values. You can use a shift left 4 bits to move the high nibble into place in each byte. I would use something like this.
// 3 is the HIGH nibble
byte firstByte = 3;
// shift into place
firstByte = firstByte << 4;
// OR with the LOW nibble
firstByte = firstByte | 5;
// do the same for the rest of the three bytes, then
digitalWrite(SS,LOW);
delayMicroseconds(1);
// send the first two nibbles
SPI.transfer(firstByte);
// send the second two nibbles
SPI.transfer(secondByte);
// send the third two nibbles
SPI.transfer(thirdByte);
// done
digitalWrite(SS,HIGH);