my first big project - BMS - is it possible?

This is the system I was discussing.
The MAX6921 might be used, or the other demux chips discussed above.
Note how each battery is connected to nothing until a relay is closed.
A change is needed in the the Gnd for the battery WOULD NOT the GND for the Arduino, demux, & relay coils.
The two would be isolated so that the measuring electronics only connect to the battery under measurement +/- terminals.