If you look at DAC.cpp file in tha audio Library:
You can see, from line 42:
// Enable output channels
dacc_enable_channel(dac, 0);
dacc_enable_channel(dac, 1);
Plus the DAC peripheral is programed to output on both DACs in this Library.
Note 1: Never connect your DAC (either DAC0 or DAC1) directly to a speaker or you will burn your DAC.
Note 2: I don't know what sound quality you can get with this Library, search on the internet feed back experiences with it on a DUE.
https://forum.arduino.cc/index.php?topic=336592.0