Also worth noting that if you are using TQFP - DIP adapter the top left pins go like this
DIP - CHIP
1 - 43
2 - 44
3 - 45
4 - 46
5 - 47
6 - 48
7 - 1
8 - 2
...
23 - 17
24 - 18
and then the right side of the adapter goes (from bottom right to top right) 19-42
Sam