Your revised schematics need amending. If you are going to connect the indicator LED in series with the opto isolator, then the 1N4148 diode should be in parallel with the series combination of the indicator and the opto isolator. Otherwise, if the 80V input is reversed, you will blow the LED.
Another issue with both the original and the revised circuit is that if you reverse the 80V input, then almost the full 80V appears across the 2.2k resistor, and it will dissipate about 3W. This is a consequence of adding the zener diodes and reducing the series resistor.
You haven't told us what the forward voltage of your indicator LEDs is (or even what colour they are), so I can't calculate the exact current flowing through the circuit.