wvmarle:
That 10k resistor in the line to the LED of the first optocoupler ensures it won't light up properly if at all. Reduce that to something that provides 10-15 mA to that LED. Check data sheet for forward voltage, after that calculation of resistor value is like a regular LED.
Shoot sorry I was looking at the wrong resistor, that one is actually 220 ohm. There is only one 10k that is next to the second optocoupler sorry about that 