I've not used the TV library but I would guess that it might use specific hardware features of the host micro to generate the required signals. If that is the case, then the pins are fixed.
The documentation says:
SYNC is on OCR1A and AUDIO is on OCR2A (except on the Arduino Leonardo, where AUDIO is on OCR0A)
Hi,
the pins are fixed.
If you inform which Arduino you are using it would be easier to help you.
If it's Arduino UNO, the pins are:
"Arduino SYNC VIDEO AUDIO"
"UNO------- 9 ------ 7 ----- 11 "
There's not a lot of space on a Nano board (or most other Arduino boards) to have lots of text printed on the board next to the headers.
The 328P micro that is used in the Nano & UNO (and others) has more functionality built inside the chip than there are pins on the chip. In order to get all that functionality out, most i/o pins have more than one function.
If you read the documentation for TVOUT, you will see the actual port pins that the audio, video and sync use.
Find one of the pinout drawings for a Nano and look where PB1, PB3 and PD7 are.