Compared to the ENC28J60, the Wiznet chip has a TCP/IP stack built into the hardware. In that respect sketches written for the Wiznet will be smaller in memory than those written for the ENC28J60. The Wiznet is also capable of 100base-T.
The official Arduino ethernet shield with the Wiznet chip does not include POE capability -- that is an additional purchase for the POE add on. Note that on the RadioShack page that "w/o" means "without". The reference documentation for the ethernet shield shows what the POE module looks like (third picture). I'm not sure where those modules can be purchased.