Display 3 character wide (big) digits on 16x2 LCD

You can only have eight custom characters at any given time. Changing a custom character while it is being displayed will change what you see on the display, so you cannot display a number, redefine the custom character, then display another number on the same screen.

Since you intend to display time, is there any combination of numbers that actually need more that eight of the custom characters simultaneously? Just hours and minutes does severely limit the possible number combinations.