expected primary-expression before 'thermocouple' .... Can somebody help me?

You are missing both brackets and a semicolon in your if statement, and I assume your if statement should look like below.

void loop() {

   Serial.println(thermocouple.readCelsius());

   if (thermocouple.readCelsius() > 50)
   {
     Serial.println("Danger high Temp");
     delay(1000);
   }
}