No, PD0/PD1 are hardwired to the USB port.
I suppose you could solder some wires onto the board for PD0 and PD1 and bring those out for your own use 
No, PD0/PD1 are hardwired to the USB port.
I suppose you could solder some wires onto the board for PD0 and PD1 and bring those out for your own use