GND reference with 220V board

Although it's more or less safe to connect to that ground under normal circumstances, I would not recommend it because these circumstances can change. I'd use an optocoupler to galvanically separate your Arduino from the high voltage circuit. An analog optocoupler like this one http://www.conrad.ch/ce/de/product/140035/OPTOKOPPLER-HCNR201-000E should do the job.