HC-12 or nRF24L01

Which of these devices is better for indoor use with many walls ?

the antennas must ‘see’ each other, even if it is only via signal reflections.

Neither may work through "many walls".

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For legal transmit power level its very unlikely that either will work with 'many walls' so consider it a no.

Perhaps describe the actual project; you might know the 'walls' and how many is 'many' but for the rest of us its pure guesswork.

I would expect HC-12 to go further. For one thing, it uses a lower frequency, 433MHz Vs 2,400MHz for the nRF. Lower frequencies == longer wavelengths generally penetrate walls a little better.

Whether either will penetrate far enough in your situation...

In a home security system I intend to exchange messages between several devices within the rooms inside a house.

If your after a definative answer, then there is none.

Walls in 'houses' vary significantly in how transparent they are to RF comms.

When keeping within legal power limits, then HC-12 modules will normally have a longer range\distance than RF24 modules.

Whether even the HC-12 modules have enough range\distance for your appplication and location is guesswork, its up to you to do on-site tests.

nRF24L01 has bigger range. HC-12 D and E only work from one room to another.

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