how do I get orange on a bi colour matrix?

I am controlling a large bi colour matrix with
this board, or one similar, containing two 7219's.
This sketch

#include "LedControl.h"

/*
 Now we need a LedControl to work with.
 ***** These pin numbers will probably not work with your hardware *****
 pin 12 is connected to the DataIn 
 pin 11 is connected to the CLK 
 pin 10 is connected to LOAD 
 We have only a single MAX72XX.
 */
LedControl lc=LedControl(7,8,9,2);// pins 10=DataIn, 9=CLK, 8=LOAD + 2 MAX7221s

/* we always wait a bit between updates of the display */
unsigned long delaytime=1000;

void setup() {
  /*
   The MAX72XX is in power-saving mode on startup,
   we have to do a wakeup call
   */
  lc.shutdown(0,false);
  /* Set the brightness to a medium values */
  lc.setIntensity(0,4);
  lc.setIntensity(1,10);
//  lc.setIntensity(2,10);
  /* and clear the display */
  lc.clearDisplay(0);
}

/*
 This method will display the characters for the
 word "Arduino" one after the other on the matrix. 
 (you need at least 5x7 leds to see the whole chars)
 */
void writeArduinoOnMatrix() {
  /* here is the data for the characters */
  byte g1[]={B00011000,
             B00111000,
             B00011000,
             B00011000,
             B00011000,
             B00011000,
             B00011000,
             B00111100,};
  byte g2[]={B00111000,
             B01111100,
             B01101100,
             B00001100,
             B00011000,
             B00110000,
             B01111100,
             B01111100};           
  byte g2b[]={B00011000,
             B00100100,
             B00000100,
             B00000100,
             B00001000,
             B00010000,
             B00100000,
             B00111100};

  /* now display them one by one with a small delay */
  
  lc.shutdown(0,true);
  delay(10);
  lc.shutdown(1,false);
  delay(10);
  lc.setRow(1,0,g1[0]);
  lc.setRow(1,1,g1[1]);
  lc.setRow(1,2,g1[2]);
  lc.setRow(1,3,g1[3]);
  lc.setRow(1,4,g1[4]);
  lc.setRow(1,5,g1[5]);
  lc.setRow(1,6,g1[6]);
  lc.setRow(1,7,g1[7]);
  delay(delaytime);
  lc.shutdown(1,true);
  delay(10);
  lc.shutdown(0,false);
  delay(10);
  lc.setRow(0,0,g2[0]);
  lc.setRow(0,1,g2[1]);
  lc.setRow(0,2,g2[2]);
  lc.setRow(0,3,g2[3]);
  lc.setRow(0,4,g2[4]);
  lc.setRow(0,5,g2[5]);
  lc.setRow(0,6,g2[6]);
  lc.setRow(0,7,g2[7]);
  delay(delaytime);
   lc.shutdown(0,true);
  delay(10);
  lc.shutdown(1,false);
  delay(10);
  lc.setRow(1,0,g2b[0]);
  lc.setRow(1,1,g2b[1]);
  lc.setRow(1,2,g2b[2]);
  lc.setRow(1,3,g2b[3]);
  lc.setRow(1,4,g2b[4]);
  lc.setRow(1,5,g2b[5]);
  lc.setRow(1,6,g2b[6]);
  lc.setRow(1,7,g2b[7]);
  delay(delaytime);

}
void loop() { 
  writeArduinoOnMatrix();

}

runs red and green but I can't find anywhere that mentions putting both leds on at the same time and getting orange?
The library cpp file gives reference to addr but I can see nowhere that addr is addressed?

I have tried changing LedControl lc=LedControl(7,8,9,2) to (7,8,9,3), adding lc.shutdown(0,true);
lc.shutdown(2,false); and each of the ic,setRow's to (addr=2) but the screen just goes blank.

I have read somewhere that you have to make one shutdown true before you can make another one false so I don't want to make 0 and 1 false but I can't see any other way of getting orange?

Please show the wiring of your bi-color matrix and the actual board you are using. A diagram of how anodes and cathodes are arranged would be helpful in seeing what is possible.

I am controlling a large bi colour matrix with
this board, or one similar, containing two 7219's.

In electronics, similar doesn't cut it. We need to know what you have, so a link to a single colour matrix board is useless when the question is about a totally different board.

The image below is taken from here

The web site gives more information but nothing about running one display so that it shows orange.

The programme actually works quite well but no orange.

Your code only declares one matrix. You've got two MAX7219's, read the LEDControl manual and address them separately. Then you can send commands as two separate devices and maybe figure out what you want to do.