How to add or assign modbusSlave ID more than one

You shouldn't use the ArduinoModbus library on AVR Arduinos as it's designed for MKR Arduinos (which have a lot more RAM).

This is only a convention used by some PLC vendors. It's not part of the Modbus standard you can use any address for any type of register. Unfortunately some PLC vendors even don't use the higher register numbers but use the range only to select the type of register, so that 30001 effectively is input register 1.