How to control direct on line 3 phase motor starter (for 3hp motor) with arduino,can L1,L2,L3 controlled by relays.If yes what should be the specification of relay
Yes.. but..
to switch the 3-phase motor current you need a special high power relay called a contactor.
These generally have a 240vac ( 110ac in the states) coil, which you can drive with either an ordinary relay or a solid-state-relay (SSR) whose coil/opto input is driven via a transistor from the arduino output.
regards
Allan