How to split a char array?

Probably, you are looking for something like:

The Codes:

uint8_t serialBytes[] = //arbitrary data in 2's complement form
{
  0xC0, 0x00, 0x00,  //header 3-byte
  0xFF, 0x60, 0xAD,   //Ch-1  //FF60AD = -40787.00
  0x12, 0x34, 0x56,   //Ch-2  //123456 = 1193046.00
  0x78, 0x9A, 0xAB,   //Ch-3  //789AAB = 7903915.00
  0xCD, 0xEF, 0xF0,   //Ch-4  //CDEFF0 = -3280912.00
  0x80, 0x83, 0x98,   //Ch-5  //808398 = -8354920.00
  0xCC, 0xBD, 0x1C,   //Ch-6  //CCBD1C = -3359460.00
  0x3B, 0xEF, 0xFE,   //Ch-7  //3BEFFE = 3928062.00
  0x45, 0xDC, 0x57    //Ch-7  //45DC57 = 4578391.00
};

float storeVoltage[8];  //save Ch0-Ch7 values as decimal numbers

uint32_t myData[8] = {0};  //save 8-Channel data as bits

void setup()
{
  Serial.begin(9600);
}
void loop()
{
  for (int i = 1, j = 0; i <= 8, j < 8; i++, j++)  //form binary bits
  {
    myData[j] = (uint32_t)(serialBytes[3 * i]) << 16 |
                (uint32_t)(serialBytes[3 * i + 1]) << 8 |
                (uint32_t)(serialBytes[3 * i + 2]);
  }
  Serial.print("Arbitrary Channel Data in 2's Complenet Form:");
  for (int j = 0; j < 8; j++)
  {
    Serial.print((myData[j]& 0x00FFFFFF), HEX); Serial.print("  ");
  }
  Serial.println();
  Serial.println("-------------------------------------------------------");
  findVoltage();  //save above binary bits as decimal values (Ch0-Ch7)
  delay(5000);
  Serial.println("============================================================================");
}

void findVoltage()
{
  for (int i = 0; i < 8; i++)
  {
    bool n = bitRead(myData[i], 23);  //reading bit-27 for 0 (+ve) or 1(-ve)
    float x1 = -n * pow(2, 23); //getting: -1*2^23
    Serial.print("Ch-"); Serial.print(i);
    Serial.print(":Magnitude of MSB: ");
    Serial.print(x1, 2);  //-8388608.00
    Serial.print("\t");
    uint32_t x2 = myData[i] & 0x007FFFFF;
    float x3 = (float)x2;
    // Serial.println(x3, 2); //+8347821.00 = 7F60AD
    storeVoltage[i] = (x1 + x3);
    Serial.print("Final Value of Channel Volatge: ");
    Serial.println(storeVoltage[i], 2);//(x1 + x3), 2); //-40787.00 = FF60AD (2's complement form)
  }
}