LED doesnt turn ON (or OFF)

Sorry I don't understand that.

Not to worry there is no reason why I should.

However the bit I don't understand is:-

but I have changed LED to be 6

So quoting from:-
http://www.arduino.cc/en/Reference/PortManipulation

PORTB maps to Arduino digital pins 8 to 13 The two high bits (6 & 7) map to the crystal pins and are not usable

So I don't see how 6 could possibly work, you are targeting the wrong bit.