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how to program arduino with five analog inputs in adafruit motorsheild?

You could program it with the IDE. All sarcasm aside, we need more info. What are the inputs? What Arduino? What is your end result? Have you tried to do it yourself? Where did you fail? Have you tried example sketches? What happened when you tried them? and so on, and so on...

http://www.catb.org/~esr/faqs/smart-questions.html