slipstick:
The difference in lifetime between a lipo charged to 4.200V and 4.201V is going to be somewhere between zero and unmeasurable. Unless of course you have some scientific (and I don't mean anecdotal) evidence showing otherwise?
It's also very unlikely that your multimeter can measure to anywhere near that accuracy. Even a well-calibrated top-end Fluke has a basic accuracy of usually +/-0.1%+1 digit so when measuring 4.200V it could read 0.005V out, plus or minus.
You may be rather overthinking this.
Steve
It's a fluke 287. yes it can, look it up or get one yourself if you don't believe me. (Or I can send a photo, if I must and if I can.) And it has an accuracy of 0.025% ish (on lower voltages atleast.)
Still though, I like precise measurements because I like consistency in my flights and as I also said, I like building even though my charger suffices, and while a millivolt over 4.2 is negligible in damage, I still like to take care of my batteries and I do like precision, is that such a sin? 
vinceherman:
I agree that the difference in the 2 chargers will make very little difference in cell health. Current draw and minimum voltage on discharge will be a much bigger impact.
But if you want to pursue, I think there are external ADC units with greater precision.
Edit: I googled 'analog to digital 24 bit' and found many examples.
it depends on the charger. some chargers can be calibrated. some cant. my imax b6ac (it has 5% accuracy components on the inside instead of 1%) only charges to between 4.174v and 4.186 randomly and I lost 1 minute and 30 seconds of flight time (and it damaged one of my cells because the battery was so inbalanced and during use that cell got pulled down to 2v while others stayed at 3.5 ish volts) compared to my antimatter charger which charges to 4.20 ish when I calibrated it, give or take 5 or so millivolts.
It's a tad more complicated than just saying "the difference is neglegible" or "the different between 2 chargers are neglegible" because there are many factors involved
Thats another reason I hope to build my own charger, because then I know I can calibrate it myself and now have to spend more than I already have in things that... really disappointed me, except for my antimatter charger.
is it so wrong to want to build something better?
Thanks for the info though, I will check those out and see what I find.