Using only the 5V from USB (before I was using a LiPo Battery), I get:
I am setup like D6: PIN to LED+ to R to GND
Vcc to GND=3.29V
LED = 1.92V
220ohm = 0.54V
Current = 5.25mA
I get this on Pins 0,1,2,3,4 and 5. Only Pin 0 was part of the initial experiment.