I find 0.8mm to be the most generally useful size, and a set of 0.6, 0.8, and 1.0mm covers almost everything.
(you need the larger size for those square-pin headers, and the smaller size is nice for vias.)
0.8mm is also almost exactly 1/32 inch, and/or a #68 drill.
Oh, a box like that is fine. When you figure out which ones you like best, you can get a boxes of 10 or 50 of just that size, but it's always good to have an assortment around as well.
(I find the itty bitty tiny ones (0.5mm and less) to be so fragile as to be nearly useless.)
Carbide drill bits are great; industrial "standard" practices call for them to be thrown away by the pros when there is still lots of life in them for us amateurs, and they show up at great prices on eBay and etc. Needing to buy brand new carbide bits can be a real eye-opener (wallet-opener ?)!