output frequency

Hi
arduino pro mini has 16MHz of processing frequency, but
what is its output frequency?

You have to be more specific. Do you wish to know the maximum speed a pin can be toggled or the frequency of the PWM pins? You could be asking about the fastest baud rate that can be achieved.

shortest time output between each pin

shortest time output between each pin? what are you trying to ask?

if you are asking how long it takes for the microcontroller to complete a given instruction, you will have to look at the Atmel's 8-bit AVR instruction set. Some instructions may take just one cycle, some take more.

1 cycle = 1/16000000 Hz = 0.0000000625 seconds = 62.5 nanoseconds

You can set the output for the PWM pins. I'm confused as well as to what you're asking but this might answer your question?