No, no, don't tie it to ground. Where does it say that? SPI.begin () sets it to an output and sets it high. If you have tied it to ground you will overload the pin.
On page 171 of the Atmega328 docs it says:
When the SPI is configured as a Master (MSTR in SPCR is set), the user can determine the direction of the SS pin.
If SS is configured as an output, the pin is a general output pin which does not affect the SPI system. Typically, the pin will be driving the SS pin of the SPI Slave.
So you have to have it as an output, but it can be used for any purpose. One possible purpose is as a SS pin for one of your devices. However any other output purpose would be OK.