Problems with ATTiny and it's ADC's

Sounds like memory failed me on that old thread.

Without actually testing it, I believe the analog channels are 0 through 3, which might be why "4" has an issue. The pin numbers below are the DIP pin numbers:

ADC0  Pin1  PB5 (RESET)
ADC1  Pin7  PB2
ADC2  Pin3  PB4
ADC3  Pin2  PB3