Save HEX data in an array to send by Xbee

Try this sketch

#include <SafeString.h>
#include <Wire.h>
//#include <TimeLib.h>
//#include <DS1307RTC.h>
#include <SoftwareSerial.h>

byte packet1[] = {0x7E, 0x00, 0x21}; //Byte delimitador y Longitud de trama
byte packet2[] = {0x10, 0x01, 0x00, 0x13, 0xA2, 0x00, 0x41, 0x4E, 0xF1, 0x24, 0xFF, 0xFE, 0x00, 0x00,}; //Id de trama, tipo de trama, direccion de 64bits, opciones y numero de brincos.

// 00:11:46 05/01/2021 == 19 chars
byte fullPacket[3 + 14 + 19 + 1];// (start + length) + (type+address) + date + checksum = 37
// length of data, including mode and address but witout checksum
// without checksum length is 33 = 0x21

char buffer [25]; // 19 for date  +1 for terminating '\0' so 25 should be OK

#define DEBUG SafeString::Output

void setup() {
  Serial.begin(9600);
  for (int i = 10; i > 0; i--) {
    Serial.print(' '); Serial.print(i);
    delay(500);
  }
  Serial.println();
  Serial.println("DS1307RTC convertir valores a HEX");
  Serial.println("-------------------");
  // comment this line out to remove error msgs and debug output
  SafeString::setOutput(Serial); // for error msgs and debug
}


void loop() {

  //tmElements_t tm;
  //if (RTC.read(tm)) {
  if (1) {
    // sprintf(buffer, "%02d:%02d:%02d %02d/%02d/%04d", tm.Hour , tm.Minute, tm.Second, tm.Day, tm.Month, tmYearToCalendar(tm.Year));
    sprintf(buffer, "%02d:%02d:%02d %02d/%02d/%04d", 5 , 6, 7, 8, 9, 2021);
    Serial.println(buffer); // con este print compruebo que la fecha y hora
    // build fullpacket
    size_t idx = 0;
    memmove(fullPacket + idx, packet1, sizeof(packet1));
    idx += sizeof(packet1);
    memmove(fullPacket + idx, packet2, sizeof(packet2));
    idx += sizeof(packet2);
    if ((idx + 19 + 1) > sizeof(fullPacket)) {
      // fullPacket size wrong
      Serial.println(F("fullPacket size wrong"));
    }
    memmove(fullPacket + idx, buffer, 19);
    idx += 19;
    // should have just one byte left for check sum
    if ((idx + 1) != sizeof(fullPacket)) {
      // fullPacket size wrong
      Serial.println(F("fullPacket size wrong"));
    }

    int chksum = 0;
    for (size_t i = 3; i < idx; i++) { // skip frame start and length, stop before last byte (the checksum
      chksum += fullPacket[i]; // will wrap around
    }
    chksum = (0xff & chksum);
    chksum = (0xff) & (0xff - chksum);
    fullPacket[idx] = chksum;
    idx++; // the total length of the full packet
    if (idx != sizeof(fullPacket)) {
      Serial.println(F("fullPacket size error"));
    }

    // print out packet
    size_t printSize = idx * 3; // ..<space>
    cSF(sfPacket, printSize);
    for (size_t i = 0; i < idx; i++) {
      //sfPacket += "0x";
      if (fullPacket[i] < 16) {
        sfPacket += '0'; // add leading 0
      }
      sfPacket.print(fullPacket[i], HEX); // you can print to SafeStrings
      sfPacket.print(' ');
    }
    Serial.println(sfPacket);

    //    xbee.write (fullpacket , idx);    O los concateno y los mando juntos.
    delay(10000);
  }
}