Serial monitor command input with code

Hello, thanks for the quick reply.
I see. At the moment I'm only sending a simple 'a' instead of the command itself from the pi.

This is the .cpp that comes with the DFRobot code

/*
 * file DFRobot_PH.cpp * @ https://github.com/DFRobot/DFRobot_PH
 *
 * Arduino library for Gravity: Analog pH Sensor / Meter Kit V2, SKU: SEN0161-V2
 *
 * Copyright   [DFRobot](http://www.dfrobot.com), 2018
 * Copyright   GNU Lesser General Public License
 *
 * version  V1.0
 * date  2018-04
 */


#if ARDUINO >= 100
#include "Arduino.h"
#else
#include "WProgram.h"
#endif

#include "DFRobot_PH.h"
#include <EEPROM.h>

#define EEPROM_write(address, p) {int i = 0; byte *pp = (byte*)&(p);for(; i < sizeof(p); i++) EEPROM.write(address+i, pp[i]);}
#define EEPROM_read(address, p)  {int i = 0; byte *pp = (byte*)&(p);for(; i < sizeof(p); i++) pp[i]=EEPROM.read(address+i);}

#define PHVALUEADDR 0x00    //the start address of the pH calibration parameters stored in the EEPROM


DFRobot_PH::DFRobot_PH()
{
    this->_temperature    = 25.0;
    this->_phValue        = 7.0;
    this->_acidVoltage    = 2032.44;    //buffer solution 4.0 at 25C
    this->_neutralVoltage = 1500.0;     //buffer solution 7.0 at 25C
    this->_voltage        = 1500.0;
}

DFRobot_PH::~DFRobot_PH()
{

}

void DFRobot_PH::begin()
{
    EEPROM_read(PHVALUEADDR, this->_neutralVoltage);  //load the neutral (pH = 7.0)voltage of the pH board from the EEPROM
    Serial.print("_neutralVoltage:");
    Serial.println(this->_neutralVoltage);
    if(EEPROM.read(PHVALUEADDR)==0xFF && EEPROM.read(PHVALUEADDR+1)==0xFF && EEPROM.read(PHVALUEADDR+2)==0xFF && EEPROM.read(PHVALUEADDR+3)==0xFF){
        this->_neutralVoltage = 1500.0;  // new EEPROM, write typical voltage
        EEPROM_write(PHVALUEADDR, this->_neutralVoltage);
    }
    EEPROM_read(PHVALUEADDR+4, this->_acidVoltage);//load the acid (pH = 4.0) voltage of the pH board from the EEPROM
    Serial.print("_acidVoltage:");
    Serial.println(this->_acidVoltage);
    if(EEPROM.read(PHVALUEADDR+4)==0xFF && EEPROM.read(PHVALUEADDR+5)==0xFF && EEPROM.read(PHVALUEADDR+6)==0xFF && EEPROM.read(PHVALUEADDR+7)==0xFF){
        this->_acidVoltage = 2032.44;  // new EEPROM, write typical voltage
        EEPROM_write(PHVALUEADDR+4, this->_acidVoltage);
    }
}

float DFRobot_PH::readPH(float voltage, float temperature)
{
    float slope = (7.0-4.0)/((this->_neutralVoltage-1500.0)/3.0 - (this->_acidVoltage-1500.0)/3.0);  // two point: (_neutralVoltage,7.0),(_acidVoltage,4.0)
    float intercept =  7.0 - slope*(this->_neutralVoltage-1500.0)/3.0;
    //Serial.print("slope:");
    //Serial.print(slope);
    //Serial.print(",intercept:");
    //Serial.println(intercept);
    this->_phValue = slope*(voltage-1500.0)/3.0+intercept;  //y = k*x + b
    return _phValue;
}


void DFRobot_PH::calibration(float voltage, float temperature,char* cmd)
{
    this->_voltage = voltage;
    this->_temperature = temperature;
    strupr(cmd);
    phCalibration(cmdParse(cmd));  // if received Serial CMD from the serial monitor, enter into the calibration mode
}

void DFRobot_PH::calibration(float voltage, float temperature)
{
    this->_voltage = voltage;
    this->_temperature = temperature;
    if(cmdSerialDataAvailable() > 0){
        phCalibration(cmdParse());  // if received Serial CMD from the serial monitor, enter into the calibration mode
    }
}

boolean DFRobot_PH::cmdSerialDataAvailable()
{
    char cmdReceivedChar;
    static unsigned long cmdReceivedTimeOut = millis();
    while(Serial.available()>0){
        if(millis() - cmdReceivedTimeOut > 500U){
            this->_cmdReceivedBufferIndex = 0;
            memset(this->_cmdReceivedBuffer,0,(ReceivedBufferLength));
        }
        cmdReceivedTimeOut = millis();
        cmdReceivedChar = Serial.read();
        if (cmdReceivedChar == '\n' || this->_cmdReceivedBufferIndex==ReceivedBufferLength-1){
            this->_cmdReceivedBufferIndex = 0;
            strupr(this->_cmdReceivedBuffer);
            return true;
        }else{
            this->_cmdReceivedBuffer[this->_cmdReceivedBufferIndex] = cmdReceivedChar;
            this->_cmdReceivedBufferIndex++;
        }
    }
    return false;
}

byte DFRobot_PH::cmdParse(const char* cmd)
{
    byte modeIndex = 0;
    if(strstr(cmd, "ENTERPH")      != NULL){
        modeIndex = 1;
    }else if(strstr(cmd, "EXITPH") != NULL){
        modeIndex = 3;
    }else if(strstr(cmd, "CALPH")  != NULL){
        modeIndex = 2;
    }
    return modeIndex;
}

byte DFRobot_PH::cmdParse()
{
    byte modeIndex = 0;
    if(strstr(this->_cmdReceivedBuffer, "ENTERPH")      != NULL){
        modeIndex = 1;
    }else if(strstr(this->_cmdReceivedBuffer, "EXITPH") != NULL){
        modeIndex = 3;
    }else if(strstr(this->_cmdReceivedBuffer, "CALPH")  != NULL){
        modeIndex = 2;
    }
    return modeIndex;
}

void DFRobot_PH::phCalibration(byte mode)
{
    char *receivedBufferPtr;
    static boolean phCalibrationFinish  = 0;
    static boolean enterCalibrationFlag = 0;
    switch(mode){
        case 0:
        if(enterCalibrationFlag){
            Serial.println(F(">>>Command Error<<<"));
        }
        break;

        case 1:
        enterCalibrationFlag = 1;
        phCalibrationFinish  = 0;
        Serial.println();
        Serial.println(F(">>>Enter PH Calibration Mode<<<"));
        Serial.println(F(">>>Please put the probe into the 4.0 or 7.0 standard buffer solution<<<"));
        Serial.println();
        break;

        case 2:
        if(enterCalibrationFlag){
            if((this->_voltage>1322)&&(this->_voltage<1678)){        // buffer solution:7.0{
                Serial.println();
                Serial.print(F(">>>Buffer Solution:7.0"));
                this->_neutralVoltage =  this->_voltage;
                Serial.println(F(",Send EXITPH to Save and Exit<<<"));
                Serial.println();
                phCalibrationFinish = 1;
            }else if((this->_voltage>1854)&&(this->_voltage<2210)){  //buffer solution:4.0
                Serial.println();
                Serial.print(F(">>>Buffer Solution:4.0"));
                this->_acidVoltage =  this->_voltage;
                Serial.println(F(",Send EXITPH to Save and Exit<<<")); 
                Serial.println();
                phCalibrationFinish = 1;
            }else{
                Serial.println();
                Serial.print(F(">>>Buffer Solution Error Try Again<<<"));
                Serial.println();                                    // not buffer solution or faulty operation
                phCalibrationFinish = 0;
            }
        }
        break;

        case 3:
        if(enterCalibrationFlag){
            Serial.println();
            if(phCalibrationFinish){
                if((this->_voltage>1322)&&(this->_voltage<1678)){
                    EEPROM_write(PHVALUEADDR, this->_neutralVoltage);
                }else if((this->_voltage>1854)&&(this->_voltage<2210)){
                    EEPROM_write(PHVALUEADDR+4, this->_acidVoltage);
                }
                Serial.print(F(">>>Calibration Successful"));
            }else{
                Serial.print(F(">>>Calibration Failed"));
            }
            Serial.println(F(",Exit PH Calibration Mode<<<"));
            Serial.println();
            phCalibrationFinish  = 0;
            enterCalibrationFlag = 0;
        }
        break;
    }
}

And this is the library that also comes with the code jus in case you also need it.

/*
 * file DFRobot_PH.h * @ https://github.com/DFRobot/DFRobot_PH
 *
 * Arduino library for Gravity: Analog pH Sensor / Meter Kit V2, SKU: SEN0161-V2
 *
 * Copyright   [DFRobot](http://www.dfrobot.com), 2018
 * Copyright   GNU Lesser General Public License
 *
 * version  V1.0
 * date  2018-04
 */

#ifndef _DFROBOT_PH_H_
#define _DFROBOT_PH_H_

#if ARDUINO >= 100
#include "Arduino.h"
#else
#include "WProgram.h"
#endif

#define ReceivedBufferLength 10  //length of the Serial CMD buffer

class DFRobot_PH
{
public:
    DFRobot_PH();
    ~DFRobot_PH();
    void    calibration(float voltage, float temperature,char* cmd);  //calibration by Serial CMD
    void    calibration(float voltage, float temperature);
    float   readPH(float voltage, float temperature); // voltage to pH value, with temperature compensation
    void    begin();   //initialization

private:
    float  _phValue;
    float  _acidVoltage;
    float  _neutralVoltage;
    float  _voltage;
    float  _temperature;

    char   _cmdReceivedBuffer[ReceivedBufferLength];  //store the Serial CMD
    byte   _cmdReceivedBufferIndex;

private:
    boolean cmdSerialDataAvailable();
    void    phCalibration(byte mode); // calibration process, wirte key parameters to EEPROM
    byte    cmdParse(const char* cmd);
    byte    cmdParse();
};

#endif