The "Wire" library doesn't work with a 'tiny85, (no hardware I2C, only a Universal Serial Interface). You'll need an alternative library, perhaps "TinyWireM".
Regarding "SoftwareSerial", this compiles fine for me with a 'tiny85 as the target:-
#include <SoftwareSerial.h>
#define rxPin 3
#define txPin 4
SoftwareSerial mySerial(rxPin, txPin);
void setup()
{
mySerial.begin(9600);
}
void loop(){}