Yes, just use the Arduino example blink program, just changing the digital pin number used from 13 to 20 and then 21. The pin(s) should toggle and can be verifed either with a DC meter, LED/resistor or O-scope.
For a short test, you could just wire a jumper from pins 20 or 21 to pin 13 and observe the built in LED, as by default pin 13 will be a input and no harm will be done by wiring those pins to 13. The LED should blink just as if pin 13 was outputting.
Thanks Ret!
I just tried it and yes, both pins change state. So now I am thinking I killed my RTC. It's a DS1307. It WAS working! Sat on the bench too long and prob got zapped.