Trouble getting simple I2C transmission on Due

For my first Arduino project I just want to communicate with an Analog Devices ADC/DAC using I2C. Before getting that far, I wanted to check that the communication coming out of the Arduino is what I would expect. I'm using SDA/SCL (not the second TWI available on the Due) so there should be no need for any pull up resistors or anything. As far as I understand I should be able to simply call the wire library and run the master_writer sketch and observe the output on an oscilloscope (there is no slave device connected at this point). Here's the code I'm using

#include <Wire.h>

void setup()
{
  Wire.begin(); // join i2c bus (address optional for master)
}

void loop()
{
  Wire.beginTransmission(4); // transmit to device #4
  Wire.write(5);        // 
  Wire.endTransmission();    // stop transmitting

  delay(500);
}

On the oscilloscope what I think I should see is two bytes go out, one with the device address, and one with my 'data'. All I'm seeing is the device address, nothing I 'write' makes it out. I've attached a screen shot from the oscilloscope. The yellow is SCL, and green is SDA. As I change the address, the green profile changes, but nothing is impact if I change what is being 'written'. I'm stumped. I've done some reading and searching to see if there is any known issue that would cause this but I haven't come up with anything.

Any help would be appreciated.
Thanks,
Andrew

Anyone?

Do you have the slave device connected as well as the scope? The master waits for an ACK to come back from the device. The bus is locked until it sees that ACK.

I did originally, but had screwed up the device address, so didn't receive the acknowledge bit. After that I had disconnected the slave in order to troubleshoot. Stumbled across this last night after fiddling with the I2C Scanner sketch that's out there.

Thanks for your help!