Each node has a unique address, and you set that up according to the info above, so the root node is Octal0
O for octal (base 8 where 8=O10).
they are in a tree structure, and each node can have upto 5 children (nodes hanging directly off the same parent)
/*
Copyright (C) 2012 James Coliz, Jr. <maniacbug@ymail.com>
This program is free software; you can redistribute it and/or
modify it under the terms of the GNU General Public License
version 2 as published by the Free Software Foundation.
Update 2014 - TMRh20
*/
#include <RF24Network.h>
#include <RF24.h>
#include <SPI.h>
RF24 radio(9,10); // nRF24L01(+) radio attached using Getting Started board
RF24Network network(radio); // Network uses that radio
const uint16_t this_node = 0; // Address of our node
const uint16_t other_node = 1; // Address of the other node
struct payload_t { // Structure of our payload
unsigned long ms;
unsigned long counter;
};
void setup(void)
{
Serial.begin(57600);
Serial.println("RF24Network/examples/helloworld_rx/");
SPI.begin();
radio.begin();
network.begin(/*channel*/ 90, /*node address*/ this_node);
}
void loop(void){
network.update(); // Check the network regularly
while ( network.available() ) { // Is there anything ready for us?
RF24NetworkHeader header; // If so, grab it and print it out
payload_t payload;
network.read(header,&payload,sizeof(payload));
Serial.print("Received packet #");
Serial.print(payload.counter);
Serial.print(" at ");
Serial.println(payload.ms);
}
}
RF24 radio(9,10); // nRF24L01(+) radio attached using Getting Started board
Declares an instance of a network node attached to pins 9,10
RF24Network network(radio); // Network uses that radio
Declares a network which includes the node
void setup(void)
{
Serial.begin(57600);
Serial.println("RF24Network/examples/helloworld_rx/");
SPI.begin();
radio.begin();
network.begin(/*channel*/ 90, /*node address*/ this_node);
}
setup begins the network on channel 90 and includes the node 'this_node' which was declared and assigned by,
const uint16_t this_node = 0; // Address of our node
so each node is attached to an arduino and as they start up and run each one shouts out here i am number X on channel 90... 
the actual checking and processing of the trafic is done by executing the RF24Network::update() command
on the board attached to each node, so if u have a message to send to node Y send it using RF24Network::write() and trust to the network gods ;).. Or dig deeper..
beyond which i cant help much as i am not using these in my project and i still have my own homework to do. Im not using such well documented libs with some of my selected h/w 
if you still dont get it either use the examples to knock up a 3 none network with lots of embedded serial writes so you can track what and how the code flows.
Or try asking specific questions..
remeber when using a library with little or no documentation you can always look in the .h file for all the public declarations and probably a good explaination as to whats what.
** edit, perhaps you dont get how the network knows how to direct the traffic 'undr the hood', thats down to the trees structure of the nodes and the known addressing format
1 parent/5 children and octal addressing protocol..