So the working code should be :
Serial.begin(112500);
//unsigned long LongVar1;
uint32_t LongVar1;
for (byte s=0 ; s<24 ; s++)
{
Serial.print(" 1 << ");
Serial.print(s);
Serial.print(" => ");
LongVar1 = 1UL << s;
Serial.println(LongVar1,BIN);
}