If I use a voltage divider to get maybe 0.05v on the aref pin, in theory I should be able to measure voltages down to around +/-0.0001v kind of range (ball park figure). Is this genuinely possible? It sounds to good to be true, and I can't find any literature in the datasheet to either confirm or deny it.
The only way to measure voltages (with an a2d) down to the tenth of a millivolt range with any accuracy is to use an amplifier and measure the amplified voltage