Wire library syntax and variables TWAR, TWCR, TWDR, twi_slarw

What you want to do is not possible using the ATmega328p hardware I2C. If you want to do this, use a software implementation of the I2C protocol (p.e. in the playground: http://playground.arduino.cc/Main/SoftwareI2CLibrary).
Before you try to change that library get familiar with I2C and all it's details because otherwise you may break the whole bus.