ESP32 does not transmit in ESP NOW protocol

It's in the header file, esp_now.h (hover over the file name in the #include statement, right-click, and choose Go to Definition)

#define ESP_ERR_ESPNOW_BASE         (ESP_ERR_WIFI_BASE + 100) /*!< ESPNOW error number base. */
#define ESP_ERR_ESPNOW_NOT_INIT     (ESP_ERR_ESPNOW_BASE + 1) /*!< ESPNOW is not initialized. */
#define ESP_ERR_ESPNOW_ARG          (ESP_ERR_ESPNOW_BASE + 2) /*!< Invalid argument */
#define ESP_ERR_ESPNOW_NO_MEM       (ESP_ERR_ESPNOW_BASE + 3) /*!< Out of memory */
#define ESP_ERR_ESPNOW_FULL         (ESP_ERR_ESPNOW_BASE + 4) /*!< ESPNOW peer list is full */
#define ESP_ERR_ESPNOW_NOT_FOUND    (ESP_ERR_ESPNOW_BASE + 5) /*!< ESPNOW peer is not found */
#define ESP_ERR_ESPNOW_INTERNAL     (ESP_ERR_ESPNOW_BASE + 6) /*!< Internal error */
#define ESP_ERR_ESPNOW_EXIST        (ESP_ERR_ESPNOW_BASE + 7) /*!< ESPNOW peer has existed */
#define ESP_ERR_ESPNOW_IF           (ESP_ERR_ESPNOW_BASE + 8) /*!< Interface error */

You can find the value of ESP_ERR_WIFI_BASE the same way. Then:

Hint 1: 100 in hex is 0x64.

Hint 2: no esp_now_add_peer calls in your sketch.