Best solution: put the pH probe on a fully isolated circuit. So isolated power supply & isolated communication.
I just finished designing a board that should be able to do pH and EC... two isolated circuits, two MCUs & two optocouplers to get the data out... hope it's finally going to work this time around. Not easy or straightforward to do.
That optocoupler is to totally electrically isolate the MCU that reads the sensor from the outside world. No electric connections whatsoever.
You can accomplish the same by running the Arduino off batteries, and make sure the only electrical connection (including signal wires via other peripherals) to the water is the pH probe. Or mains powered and have absolutely nothing else to do with electricity touch the body of water you're measuring.
EC is what? Electrical conductivity?
pH and conductivity can be measured successfully in water by keeping everything separate.
Individual pH and conductivity meters, portable, battery powered will work without interference provided they are not connected through common grounds.
A pH probe with a FET amplifier will run on a battery for a long time. Conductivity ideally needs an AC source but for short periods, DC will do. A couple of stainless steel probes on a multimeter in resistance mode will work.
Water quality monitoring equipment routinely has anything up to six probes in a single "head".
A lot more difficult if you are working with a common power supply.
Yes, EC is electric conductivity, a measure for the amount of fertiliser (mineral salts) in the solution.
If your period is shorter than about 1 ms, DC should indeed give you a reliable reading. After that, the conductivity starts to drop rapidly as the ions move around and electrolyses starts.
Commercial instruments more often than not use graphite electrodes - stainless steel, especially grades like 304 are pretty durable.
For a DIY setup, I wonder if there is any mileage in trying something like pencil leads? A softish grade - B - from something like a carpenters' pencil that has large diameter (actually oval or rectangular) leads might work.
Commercial probes have several concentric graphite electrodes like a stack of Polo mints, embedded in in insulating material like Tufnol.
Electric motor graphite brushes might be another source.