There is a .pdf that presents and explains all the available functions you can have with SimpleModbus library:
To upload the library,there is an issue (I don't know why). But, all you have to do, if you want e.g. use your DUE as a MODBUS Master is:
Open a new IDE window, name it e.g. MyModbus, then click in the little arrow in the top right of the window and select New Tab (You will see a yellow band).
Name this New file SimpleModbusMaster_DUE.h , copy and paste this file from the library into your SimpleModBusMaster_DUE.h.
Do that again but this time for SimpleModbusMaster_DUE.cpp that you will save in your SimpleModBusMaster_DUE.cpp .
Copy the sketch of the example provided. Change the include to have: #include "SimpleModBusMaster_DUE.h"
Because the library is now in the same folder as your Modbus example folder.