A bunch of my bits of hardware include SC card readers. I've been going through the SD library info. but nowhere does it talk about using multiple SD cards. It does talk about using different chip select pins.
I've never seen..
SD.begin(chipSelect1);
SD.begin(chipSelect2);
is it the case where you just have to choose one SD card reader and stick with it?
One issue that you'll run into is that the SD header file has an extern statement in it, and the source file creates an instance of the SDClass, called SD.
I don't see anything to preclude you creating another instance of SDClass, with a different name, since the source code never references the SD instance.